Green Synthesis of Nano Cobalt Oxide by using Hibiscus rosa-sinensis

Jump To References Section

Authors

  • Department of Chemistry, Presidency University, Bengaluru - 560064, Karnataka, India ,IN
  • Department of Chemistry, Presidency University, Bengaluru - 560064, Karnataka, India ,IN
  • Department of IEM, M. S. Ramaiah Institute of Technology, Bengaluru - 560054Karnataka, India ,IN

DOI:

https://doi.org/10.18311/jmmf/2023/35434

Keywords:

Green Synthesis, Hibiscus rosa-sinensis, Nano Cobalt Oxide

Abstract

This research article provides the synthesis and characterization of Cobalt Oxide nano particles by eco-friendly green chemistry method. The cobalt oxide nano particles were synthesised by using leaf extract of Hibiscus rosa-sinensis. The light violet coloured leaf extract of hibiscus rosa-sinensis was used as catalyst and stabilizer for the synthesis of nano particles from precursor cobalt chloride hexa hydrate. So obtained cobalt oxide nano particles were characterized by EDAX, SEM, XRD, FTIR, TGA. EDAX confirms the presence of cobalt and oxygen in the nano particles. SEM studies shows the sponge and few cubical spine like structure of cobalt oxide with average grain size of 60 nm. XRD studies confirms the nano size of particles and maximum peak was obtained at (311) confirms the presence of nano cobalt oxide.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Downloads

Published

2023-11-02

How to Cite

Keerthi, K., Shashikala, A. R., & Sridhar, B. S. (2023). Green Synthesis of Nano Cobalt Oxide by using <i>Hibiscus rosa-sinensis</i>. Journal of Mines, Metals and Fuels, 71(9), 1186–1190. https://doi.org/10.18311/jmmf/2023/35434

 

References

Siddique M, Ilyas M, Chiangmai MS. J. Sci. 2018; 45:1901.

Hansen TW, DeLaRiva AT, Challa SR, Datye AK. Acc. Chem. Res., 2013; 46:1720

Kolhatkar A, Jamison A, Litvinov D, Willson R, Lee T. Int. j. molec. Sci., 2013; 14:15977.

Li X, Zhang F, Zhao D. Chem Soc Rev. 2015; 44:1346.

Majidi S, Zeinali Sehrig F, Samiei M, Milani M, Abbasi E, Dadashzadeh K, Akbarzadeh A. Artif Cell Nanomed Biotechnol. 2016; 44:1186.

Gul I, Sayed M, Shah NS, Khan JA, Polychronopoulou K, Iqbal J, Rehman F. Chem Eng J. 2020; 384:123255.

Samat NA, Nor RM. Sol–gel synthesis of zinc oxide nanoparticles using citrus aurantifolia extracts. Ceram Int. 2013; 39(S):545–8.

Rajiv P, Rajeshwari S, Venckatesh R. Bio-Fabrication of zinc oxide nanoparticles using leaf extract of Parthenium hysterophorus L. and its size-dependent antifungal activity against plant fungal pathogens. Spectrochim Acta A. 2013; 112:384–7.

Gunalan S, Sivaraj R, Rajendran V. Green synthesized ZnO nanoparticles against bacterial and fungal pathogens. Prog Nat Sci Mater Int. 2012; 22:693–700.

Yan D, Zhao H, Liu Y, Wu X, Pei J. Shape-controlled synthesis of Cobalt particles by a surfactant-free solvothermal method and their catalytic application on the thermal decomposition of ammonium perchlorate. Cryst Eng Comm. 2015; 17:9062–9.

Abu-Zied BM, Alamry KA. Green synthesis of 3D hierarchical nanostructured Co3O4/carbon catalysts for the application in sodium borohydride hydrolysis. J Alloys Compd. 2019; 798:820–31.

El-Sayed, Abdelhakim HK, Zakaria Z. Extracellular biosynthesis of cobalt ferrite nanoparticles by Monascus purpureus and their antioxidant, anticancer and antimicrobial activities: Yield enhancement by gamma irradiation. Mater Sci Eng C. 2019; 107.

Lai T, Lai Y, Lee C, Shu V, Wang C. Microwave-assisted rapid fabrication of Co3O4 nanorods and application to the degradation of phenol. Catal Today. 2008; 131:105– 10.

Baydi ME, Poillerat G, Rehspringer JL., Gautier JL, Koenig JF, Chartier PA. Sol–gel route for the preparation of Co3O4 catalyst for oxygen electrocatalysis in alkaline medium. J Solid State Chem. 1994; 109:281–8.

Oh SW, Bang HJ, Bae YC, Sun YK. Effect of calcination temperature on morphology, crystallinity and electrochemical properties of nano-crystalline metal oxides (Co3O4, CuO, and NiO) prepared via ultrasonic spray pyrolysis. J Power Sources. 2007; 173:502–9.

Mane AU, Shalini K, Wohlfart A, Devi A, Shivashankar S.A. Strongly oriented thin films of Co3O4 deposited on single-crystal MgO (100) by low-pressure, low-temperature MOCVD. J Cryst Growth. 2002; 240:157–63.

Rumplecker A, Kleitz F, Salabas EL., Schüth F. Hard templating pathways for the synthesis of nanostructured porous Co3O4. Chem Mater. 2007; 19:485–96.

Mohandes F, Davar F, Salavati NM. Preparation of Co3O4 nanoparticles by nonhydrolytic thermolysis of [Co(Pht) (H2O)]n polymers. J Magn Magn Mater. 2010; 322:872– 7.

Ren L, Wang P, Han Y, Hu C, Wei B. Synthesis of CoC2O4·2H2O nanorods and their thermal decomposition to Co3O4 nanoparticles. Mater Phys Lett. 2009; 476:78–83.

Li L, Chu Y, Liu Y, Song JL, Wang D, Du XW. A facile hydrothermal route to synthesize novel Co3O4 nanoplates. Mater Lett. 2008; 62:1507–10.

Kim DY, Ju SH, Koo HY, Hong SK, Kang YC. Synthesis of nanosized Co3O4 particles by spray pyrolysis. J Alloys Compd. 2006; 417:254–8.

Gu F, Li C, Hu Y, Zhang L. Synthesis and optical characterization of Co3O4 nanocrystals. J Cryst Growth. 2007; 304:369–73.

Wang X, Chen XY, Gao LS., Zheng HG, Zhang Z, Qian YT. One-dimensional arrays of Co3O4 nanoparticles: synthesis, characterization, and optical and electrochemical properties. J Phys Chem B. 2004; 108:16401–4.

Bhatt AS, Bhat DK, Tai CW, Santosh MS. Microwave assisted synthesis and magnetic studies of cobalt oxide nanoparticles. Mater Chem Phys. 2011; 125:347–50.

Wang RM, Liu CM, Zhang HZ, Chen CP, Guo L, Xu HB, Yang SH. Porous nanotubes of Co3O4: synthesis, characterization, and magnetic properties. Appl Phys Lett. 2004; 85:2080–2.

Nethravathi C, Sen S, Ravishankar N, Rajamathi M, Pietzonka C, Harbrecht B. Ferrimagnetic nanogranular Co3O4 through solvothermal decomposition of colloidally dispersed monolayers of a-cobalt hydroxide. J Phys Chem B. 2005; 109:11468–72.

Ichiyanagi Y, Yamada S. The size-dependent magnetic properties of Co3O4 nanoparticles. Polyhedron. 2005; 24:2813–6.

Xia XH, Tu JP, Zhang J, Xiang JY, Wang XL, Zhao XB. Fast electrochromic properties of self-supported Co3O4 nanowire array film. Sol Energy Mater Sol Cells. 2010; 94:386–9.

Yu T, Zhu Y, Xu X, Shen Z, Chen P, Lim CT, Thong JTL, Sow CH. Controlled growth and field-emission properties of cobalt oxide nanowalls. Adv Mater. 2005; 17(1595–9).

Noguchi S, Mizuhashi M. Optical properties of Cr Co oxide films obtained by chemical spray deposition: substrate temperature effects. Thin Solid Films. 1981; 77:99–106.

Wang D, Wang Q, Wang T. Morphology-controllable synthesis of cobalt oxalates and their conversion to mesoporous Co3O4 nanostructures for application in supercapacitors. Inorganic Chem. 2011; 50:6482–92.

Xiao Y, Liu S, Li F, Zhang A, Zhao J, Fang S, Jia D. 3D Hierarchical Co3O4 twin spheres with an urchin-like structure: large-scale synthesis, multistep-splitting growth, and electrochemical pseudo capacitors. Adv Funct Mater. 2012; 22:4052–9.

Azizi S, et al. Effect of annealing temperature on antimicrobial and structural properties of bio-synthesized zinc oxide nanoparticles using flower extract of Anchusa italica. J Photochem Photobiol B. 2016; 161:441–9.