Simple Ions vis-à-vis Ion Pairs and Ion Triplets for Electrolytes in Pure as Well as Mixed Non-Aqueous Solvents

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Authors

  • AKPC College, Subhasnagar, Bengai, Hooghly-712611, West Bengal ,IN

DOI:

https://doi.org/10.24906/isc/2021/v35/i6/211367

Keywords:

Molar Conductance of Associated Ions, Ionic Strength, Ion Triplet, Ion Association Constant, Mixed Non-Aqueous Solvents.

Abstract

The regions of both ideal and non-ideal behaviour of electrolyte solutions containing simple ions, ion pairs or undissociated molecules, and ion triplets have been analyzed theoretically in terms of measurable electrical properties. Methods have been devised to obtain the values of different equilibrium constants and species concentrations. Effects of temperature and solvent composition on the thermodynamic properties ΔGφ, ΔHφ and ΔSφ and evaluation techniques of these quantities have been discussed. Molar conductance of some ion-triplets has also been evaluated.

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Author Biography

Swapan Kole, AKPC College, Subhasnagar, Bengai, Hooghly-712611, West Bengal

https://orcid.org/0000-0002-9436-2744

Published

2022-02-28

How to Cite

Kole, S. (2022). Simple Ions vis-à-vis Ion Pairs and Ion Triplets for Electrolytes in Pure as Well as Mixed Non-Aqueous Solvents. Indian Science Cruiser, 35(6), 23–30. https://doi.org/10.24906/isc/2021/v35/i6/211367

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References

P W Atkins, Physical Chemistry, Oxford University Press, 2002.

S Kole, Fuel Cells: Efficient Energy Conversion, Indian Science Cruiser, Vol 9, No 3, page 11-16, 1995.

D Linden (Ed.), Handbook of Batteries and Cells. McGraw-Hill, New York, 1984.

V M M Lobo, Handbook of Electrolyte Solutions, Elsevier, Amsterdam, 1989.

P J Flory, Principles of Polymer Chemistry, Cornell University Press, 1953.

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