The aggregation of 1,3,4-thiadiazole based Hockey stick shaped Mesogen in Langmuir-Blodgett thin film in comparison to that of 1,3,4-oxadiazole

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Authors

  • Alpana Baidya
     Department of Chemistry, Tripura University, Agartala – 799022, Tripura ,IN
  • Bandana Das
     Department of Chemistry, Tripura University, Agartala – 799022, Tripura ,IN
  • Santanu Majumder
     Department of Chemistry, G.D. College, Kamalpur, Harerkhola – 799285, Tripura ,IN
  • Sandip Kumar Saha
     Department of Chemistry, Assam University, Silchar – 788011, Assam ,IN
  • Ranendu K. Nath
     Department of Chemistry, Tripura University, Agartala – 799022, Tripura ,IN
  • Manoj K. Paul
     Department of Chemistry, Assam University, Silchar – 788011, Assam ,IN

DOI:

https://doi.org/10.18311/jsst/2021/28356

Keywords:

1, 3, 4-Oxadiazole Derivative, 4-Thiadiazole Derivative, Bent Core Mesogen, Langmuir Blodgett, Liquid Crystal, Thin Film
thin film, Langmuir Blodgett

Abstract

Bent Core Mesogens are remarkably interesting achiral Liquid Crystals. These grab attention for their utility. The compound, taken for investigation, is a Schiff base addition product, composed of 2-(4β-aminophenyl)-5-(4?β-butyloxyphenyl)-1,3,4- thiadiazole and 4-n-hexadecyloxy salicylaldehyde. The property of this imine derivative is in accordance with liquid crystal and is a Bent Core Mesogen (BCM). The thin layers were prepared with the help of Langmuir-Blodgett apparatus. The morphology and photo-physical characteristics of thin films were examined in comparison to similar BCM derivative of 1,3,4-Oxadiazole. The expectation was the formation of monolayer of molecules on the substrate. Practically there were layer of clusters on the substrate. Both molecules form nano clusters. The typically different aggregates by the thiadiazole moiety in comparison to oxadiazole moiety are revealed. Cluster formation is also supported by the Atomic Force Microscopic (AFM) images.

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Published

2022-05-12

How to Cite

Baidya, A., Das, B., Majumder, S., Kumar Saha, S., Nath, R. K., & Paul, M. K. (2022). The aggregation of 1,3,4-thiadiazole based Hockey stick shaped Mesogen in Langmuir-Blodgett thin film in comparison to that of 1,3,4-oxadiazole. Journal of Surface Science and Technology, 37(1-2), 43–66. https://doi.org/10.18311/jsst/2021/28356

Issue

Volume 37, Issue 1-2, June 2021

Section

Articles
Crossref
Scopus
Google Scholar
Europe PMC
Received 2021-08-08
Accepted 2022-03-23
Published 2022-05-12

 

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