Ultrasonic Velocity and Critical Micellar Concentration of Glycerol Monostearate in Mixed Organic Solvent at 290 K

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Authors

  • Kritika Sharma
     Department of Chemistry, Eternal University, Baru Sahib –173101, Himachal Pradesh ,IN
  • Sujata Negi
     Department of Chemistry, Eternal University, Baru Sahib –173101, Himachal Pradesh ,IN
  • Kamal Kishore
     Department of Chemistry, Eternal University, Baru Sahib –173101, Himachal Pradesh ,IN

DOI:

https://doi.org/10.18311/jsst/2019/16349

Keywords:

Antistaling and Antistatic agents, Emulsifiers, Nonionic Surfactants

Abstract

Density, viscosity, ultrasonic velocity and refractive index measurements of Glycerol Monostearate (GMS) in 80/20 (% v/v) benzene-methanol mixture at 290 K with varying concentrations have shown that there is noticeable variation in aggregation of non-ionic surfactant at Critical Micellar Concentration (CMC). Density and viscosity results have been satisfactorily explained by some well-known equations viz. Jones-Dole, Moulik, Vand, Einstein and Root. Jacobson model has been used to evaluate adiabatic compressibility, molar compressibility, solvation number molar sound velocity, relaxation strength, relative association and other allied acoustical constants. The variation of refractive index with concentration of GMS solutions shows a marked change in value at CMC. Treatment of data obtained from density, viscosity, ultrasonic velocity and refractive index measurements has shown that strong interaction exists between GMS and solvent molecules, and GMS molecules do not aggregate considerably in pre-micellization region.

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Published

2019-06-25

How to Cite

Sharma, K., Negi, S., & Kishore, K. (2019). Ultrasonic Velocity and Critical Micellar Concentration of Glycerol Monostearate in Mixed Organic Solvent at 290 K. Journal of Surface Science and Technology, 35(1-2), 17–25. https://doi.org/10.18311/jsst/2019/16349

Issue

Volume 35, Issue 1-2, June 2019

Section

Articles
Crossref
Scopus
Google Scholar
Europe PMC
Received 2017-06-28
Accepted 2018-12-06
Published 2019-06-25

 

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