Interaction of a Cationic Surfactant with an Oppositely Charged Polymer

Jump To References Section

Authors

  • Centre for Surface Science, Department of Chemistry, Jadavpur University, Kolkata – 700032, West Bengal ,IN
  • Centre for Surface Science, Department of Chemistry, Jadavpur University, Kolkata – 700032, West Bengal ,IN
  • Centre for Surface Science, Department of Chemistry, Jadavpur University, Kolkata – 700032, West Bengal ,IN
  • ,IN
  • Department of Chemistry, St. Francis Xavier University, Antigonish, Nova Scotia, B2G 2W5 ,CA

DOI:

https://doi.org/10.18311/jsst/2016/14746

Keywords:

Anionic Polymer, Cationic Surfactant, Electrostatic Interaction, Hydrophobic Interaction, Micellization
english

Abstract

The interactions between the cationic surfactant Dodecyltrimethylammonium Bromide (DTAB) and anionic polymer sodium carboxymethyl cellulose (Na-CMC) in aqueous medium were studied at 300K over different concentrations of Na-CMC by tensiometry, conductometry, viscometry, turbidimetry and fluorimetry. Aggregation of surfactant was attained in two steps, the first being the monomeric adsorption of surfactants on anionic sites of the polymer saturating at lower concentrations of surfactant and the second one being the formation of micelles by surfactants at higher concentrations. Mainly, two types of interactions prevailed throughout namely, electrostatic and hydrophobic interactions. Due to the variation of the interactions depending on the concentrations of polymer, there has been considerable differences in the behavioural pattern of the profiles for the lower concentrations of polymer compared to that of the upper ones.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Published

2017-04-05

How to Cite

Ghosh, S., Mal, A., Chakraborty, T., De, G. C., & Marangoni, D. G. (2017). Interaction of a Cationic Surfactant with an Oppositely Charged Polymer. Journal of Surface Science and Technology, 32(3-4), 107–114. https://doi.org/10.18311/jsst/2016/14746
Received 2017-01-31
Accepted 2017-01-31
Published 2017-04-05

 

References

S. Ghosh, J. Colloid Interface Sci., 244, 128 (2001).

D. Tikariha, K. K. Ghosh, P. Quagliotto and S. Ghosh, J. Chem. Eng. Data, 55, 4162 (2010).

S. Ghosh, A. Das Barman, G. C. De and A. R. Das, J. Phys. Chem. B, 115, 11098 (2011).

D. Tikariha, B. Kumar, S. Ghosh, A. K. Tiwari, S. K. Saha, N. Barbero, P. Quagliotto, and K. K. Ghosh, J. Nanofluids, 2, 316 (2013).

S. M. Saleem and A. Hernandez, J. Surf. Sci. Technol., 3, 1 (1987).

A. Bhattacharyya and J. F. Argillier, J. Surf. Sci. Technol., 21, 161 (2005).

D. Chandra and A. Bhaumik, Ind. Eng. Chem. Res., 45, 4879 (2006).

S. Ghosh and S. P. Moulik, Indian J. Chem. Sect. A, 38, 10 (1999).

S. Ghosh and S. P. Moulik, Indian J. Chem. Sect. A, 38, 201 (1999).

S. Ghosh and S. P. Moulik, J. Surf. Sci. Technol., 14, 110 (1998).

J. M. Landry, D. G. Marangoni, D. A. Arden, I. J. MacLennan and J. C. T. Kwak, J. Surfact. Deterg., 12, 155 (2009).

S. Ghosh, J. Surf. Sci. Technol., 19, 167 (2003).

J. M. Gohil, A. Bhattacharya and P. Roy, J. Surf. Sci. Technol., 20, 1 (2004).

D. Varade, R. Sharma, P. Majhi and P. Bahadur, J. Surf. Sci. Technol., 19, 85 (2003).

A. Rangaraj and A. K. Rakshit, J. Surf. Sci. Technol., 16, 246 (2000).

S. Chakraborty, A. K. Bera, S. Bhattacharya, S. Ghosh, A. K. Pal, S. Ghosh and A. Banerjee, J. Organomet. Chem., 645, 33 (2002).

M. Sadeghalvaad and S. Sabbaghi, J. Nanofluids, 4, 435 (2015).

L. S. Sundar, E. V. Ramana, M. K. Singh, J. Gracio and A. C. M. Sousa, J. Nanofluids, 3, 200 (2014).

A. Saxena and H. B. Bohidar, J. Surf. Sci. Technol., 13, 32 (1997).

S. Brojabasi and J. Philip, J. Nanofluids, 2, 237 (2013).

A. Nag, B. Sadhukhan and D. K. Chattoraj, J. Surf. Sci. Technol., 4, 91 (1988).

E. Staples, I. Tucker, J. Penfold, N. Warren, R. K. Thomas and D. J. F. Taylor, Langmuir, 18, 5147 (2002).

T. C. Singh, R. K. Nath, K. Manna and A. K. Panda, J. Surf. Sci. Technol., 29, 101 (2013).

M. Rodgers, C. Rodgers and R. M. Palepu, J. Surf. Sci. Technol., 20, 33 (2004).

Y. Kadam, K. Singh, D. G. Marangoni, J. H. Ma, V. K. Aswal and P. Bahadur, J. Colloid Interface Sci., 351, 449 (2010).

M. S. Kumar and H. N. Singh, J. Surf. Sci. Technol., 8, 381 (1992).

E. Halder, D. K. Chattoraj and K. P. Das, J. Surf. Sci. Technol., 19, 21 (2003).

A. A. McLachlan and D. G. Marangoni, Can. J. Chem., 88, 124 (2010).

T. C. Singh, S. Biswas, S. Dasgupta, A. Mitra, A. K. Panda and R. K. Nath, J. Surf. Sci. Technol., 24, 21 (2008).

T. Chakraborty. I. Chakraborty and S. Ghosh, Langmuir, 22, 9905 (2006).

S. Das, I. Mukherjee, B. K. Paul and S. Ghosh, Langmuir, 30, 12483 (2014).

S. Das, S. Mondal and S. Ghosh, RSC Advances, 6, 30795 (2016).

N. Jain, S. Trabelsi, S. Guillot, McLoughlin, D. Langevin, P. Letellior, M. Turmine, Langmuir, 20, 8496 (2004).

Y. Pi, Y. Shang, H. Liu, Y. Hu and J. Jiang, J. Colloid Interface Sci., 306, 405 (2007).

P. K. Jana, S. Bhattacharyya, S. Ghosh and P. Das, Int. J. Res. Chem. Environ. 5, 12 (2015).

E. K. Just and T. G. Majewicz, Encyclopedia of Polymer Science and Engineering, John Wiley and Sons, New York, 3, 226 (1985).

X. Wang, Y. Li, J. Li, J. Wang, Y. Wang, Z. Guo and H. Yan, J. Phys. Chem. B, 109, 10807 (2005).

S. Trabelsi, E. Raspand and D. Langevin, Langmuir, 23, 10053 (2007).