Synthesis and Characterization of CDS Nanoparticles from Single Molecular Complex:Bis-(Thiourea)Cadmium(II)Acetate

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Authors

  • M. N. Goswami
     Department of Physics, Midnapore College (Autonomous), Midnapore 721101 ,IN
  • Nilkamal Maiti
     Department of Chemistry, Midnapore College (Autonomous), Midnapore 721101 ,IN

DOI:

https://doi.org/10.24906/isc/2018/v32/i5/180257

Keywords:

Cadmium Acetate, Metal Complex, Solvothermal, Nanocrystallites, Absorption and Emission Spectra.

Abstract

Metal Complex,bis-(thiourea)cadmium(II) acetate, have been successfully synthesized through reaction between thiourea with cadmium acetate in 1:2 ratio and characterized by spectroscopic analysis. The obtained complexhas been used as precursor andthermolyzedat 100°Cin ethylene glycol for the growth of crystalline CdS nanocompounds without using any external capping agents. The broadening of diffraction peaks in the X-ray diffractogramdepicted the nano-sized particles. Transmission electron microscopy (TEM) providesnon-spherical and irregular aggregates of particles size about 5.5 nm which were also confirmed by the measurement of crystallite size using Scherrer equation for the peaks of XRD. The emission spectra of nano-size CdS compounds showed the red shift (606 nm) than the bulk material.

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Published

2018-09-01

How to Cite

Goswami, M. N., & Maiti, N. (2018). Synthesis and Characterization of CDS Nanoparticles from Single Molecular Complex:Bis-(Thiourea)Cadmium(II)Acetate. Indian Science Cruiser, 32(5), 30–36. https://doi.org/10.24906/isc/2018/v32/i5/180257

Issue

Volume 32, Issue 5 , September 2018

Section

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